The Formation Of Subsurface Oxygen On Pt(100)

Author(s)

H. H. Rotermund
Jochen A. Lauterbach, University of South Carolina - ColumbiaFollow
G. Haas

Document Type

Article

Subject Area(s)

Engineering, Chemical Engineering, Materials Science and Engineering, Semiconductor and Optical Materials, Structural Materials, Biotechnology

Abstract

PhotoEmission Electron Microscopy (PEEM) enables imaging a surface via its work function. If a CO covered Pt(100) surface is exposed to oxygen patches are formed which appear dark in the PEEM image due to their high work function. As the surface is heated to temperatures above 650 K we observe the conversion of these dark islands into very bright ones with work functions much lower than even that of the clean surface. These findings are attributed to a change in the dipole moment of the adsorbed oxygen induced by their migration beneath the surface. A total work-function decrease of up to 1.2 eV has been evaluated independently using a Scanning Photoemission Microscope (SPM). The properties of this new kind of oxygen were also further investigated with thermal desorption spectroscopy and with Auger-electron spectroscopy.

Digital Object Identifier (DOI)

https://doi.org/10.1007/BF00331749

Publication Info

Postprint version. Published in Applied Physics A, Volume 57, Issue 6, 1993, pages 507-511.

© Applied Physics A, 1993, Springer-Verlag

APA Citation

Rotermund, H.H., Lauterbach, A.J., Haas, G. (1993). The formation of subsurface oxygen on Pt(100). Applied Physics A, 57(6), 507-511. http://dx.doi.org/10.1007/BF00331749

Rights

© Applied Physics A, 1993, Springer-Verlag