Mathematical Model of a Lithium/Polypyrrole Cell

Author(s)

Taewhan Yeu, Texas A & M University - College Station
Ralph E. White, University of South Carolina - ColumbiaFollow

Document Type

Article

Subject Area(s)

Chemical Engineering

Abstract

A mathematical model to simulate the charge/discharge behavior of a lithium/lithium perchlorate-propylene carbonate/polypyrrole(Li/LiClO₄-PC/PPy) secondary battery cell is presented. The model can be used to gain a better understanding of the behavior of this cell and to provide guidance toward the design of new secondary batteries which utilize an electronically conductive polymer such as polypyrrole (PPy) as the cathode. The model includes the capability of handling charge and discharge behavior and is used to study the effect of various design parameters on the performance of the cell.

Publication Info

Journal of the Electrochemical Society, 1990, pages 1327-1336.

© The Electrochemical Society, Inc. 1990. All rights reserved. Except as provided under U.S. copyright law, this work may not be reproduced, resold, distributed, or modified without the express permission of The Electrochemical Society (ECS). The archival version of this work was published in the Journal of the Electrochemical Society.

http://www.electrochem.org/

DOI: 10.1149/1.2086668

http://dx.doi.org/10.1149/1.2086668

Rights

© The Electrochemical Society, Inc. 1990. All rights reserved. Except as provided under U.S. copyright law, this work may not be reproduced, resold, distributed, or modified without the express permission of The Electrochemical Society (ECS). The archival version of this work was published in the Journal of the Electrochemical Society.

http://www.electrochem.org/

DOI: 10.1149/1.2086668

http://dx.doi.org/10.1149/1.2086668