Crystal Growth of Novel Lanthanide-Containing Platinates K4[Ln6Pt2O15] (Ln = La, Pr, Nd, Sm) with a Unique Framework Structure

Document Type

Paper

Subject Area(s)

Chemistry

Abstract

Crystals of a new family of lanthanide-containing platinum oxides with a unique framework structure were grown out of molten hydroxide fluxes. The structure consists of a crystallographically well-behaved [Ln6Pt2O15]4− framework permeated by channels filled with disordered atoms along the [100] and equivalent directions. Open-channel structures are rare in oxides and apparently unknown in platinate chemistry.

Digital Object Identifier (DOI)

https://doi.org/10.1021/ic801789e

Rights

© Inorganic Chemistry 2008, American Chemical Society.

APA Citation

zur Loye, H.-C., Hansen, T., Zhao, Q., Mugavero, S., Withers, R., & Smith, M. (2008). Crystal Growth of Novel Lanthanide-Containing Platinates K4[Ln6Pt2O15] (Ln = La, Pr, Nd, Sm) with a Unique Framework Structure. Inorganic Chemistry, 48(2), 414–416. https://doi.org/10.1021/ic801789e

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