Layered Heterometallic Iodoplumbate Containing a Novel Pb3Cu6I16 Net: Structure and Optical Properties
A new heterometallic iodoplumbate was synthesized solvothermally. The complex, [Co(phen)3]2[Pb3Cu6I16]·C2H5OH, contains a novel Pb3Cu6I16 net made up of linked Pb3I11 and Cu6I11 clusters. The clusters form a BN-type layer, where the Pb3I11 and Cu6I11 clusters take the place of B and N. The layers, which are separated by [Co(phen)3]2+ cations, contain cavities in which ethanol molecules are located.
Published in Inorg. Chem, Volume 45, Issue 26, 2006, pages 10437-10439.
Layered Heterometallic Iodoplumbate Containing a Novel Pb3Cu6I16 Net: Structure and Optical PropertiesMichael C. Burns,Meredith A. Tershansy,Joseph M. Ellsworth,Zeeshan Khaliq,LeRoy Peterson, Jr.,Mark D. Smith, and, and Hans-Conrad zur Loye* Inorganic Chemistry 2006 45 (26), 10437-10439