Layered Heterometallic Iodoplumbate Containing a Novel Pb₃Cu₆I₁₆ Net: Structure and Optical Properties

Author(s)

Michael C. Burns, University of South Carolina - Columbia
Meredith A. Tershansy, University of South Carolina - Columbia
Joseph M. Ellsworth, University of South Carolina - Columbia
Zeeshan Khaliq
LeRoy Peterson Jr., Francis Marion University
Mark D. Smith, University of South Carolina - ColumbiaFollow
Hans-Conrad zur Loye, University of South Carolina - ColumbiaFollow

Document Type

Paper

Subject Area(s)

Chemistry

Abstract

A new heterometallic iodoplumbate was synthesized solvothermally. The complex, [Co(phen)₃]₂[Pb₃Cu₆I₁₆]·C₂H₅OH, contains a novel Pb₃Cu₆I₁₆ net made up of linked Pb₃I₁₁ and Cu₆I₁₁ clusters. The clusters form a BN-type layer, where the Pb₃I₁₁ and Cu₆I₁₁ clusters take the place of B and N. The layers, which are separated by [Co(phen)₃]²⁺ cations, contain cavities in which ethanol molecules are located.

Digital Object Identifier (DOI)

https://doi.org/10.1021/ic061827i

Publication Info

Published in Inorganic Chemistry, Volume 45, Issue 26, 2006, pages 10437-10439.

Rights

© Inorganic Chemistry 2006, American Chemical Society.

APA Citation

Burns, M., Terhansy, M., Ellsworth, J., Khaliq, Z., Peterson, L., Smith, M., & zur Loye, H.-C. (2006). Layered Heterometallic Iodoplumbate Containing a Novel Pb3Cu6I16 Net: Structure and Optical Properties. Inorganic Chemistry, 45(26), 10437–10439. https://doi.org/10.1021/ic061827i