Layered Heterometallic Iodoplumbate Containing a Novel Pb3Cu6I16 Net: Structure and Optical Properties

Document Type

Paper

Subject Area(s)

Chemistry

Abstract

A new heterometallic iodoplumbate was synthesized solvothermally. The complex, [Co(phen)3]2[Pb3Cu6I16]·C2H5OH, contains a novel Pb3Cu6I16 net made up of linked Pb3I11 and Cu6I11 clusters. The clusters form a BN-type layer, where the Pb3I11 and Cu6I11 clusters take the place of B and N. The layers, which are separated by [Co(phen)3]2+ cations, contain cavities in which ethanol molecules are located.

Digital Object Identifier (DOI)

https://doi.org/10.1021/ic061827i

Rights

© Inorganic Chemistry 2006, American Chemical Society.

APA Citation

Burns, M., Terhansy, M., Ellsworth, J., Khaliq, Z., Peterson, L., Smith, M., & zur Loye, H.-C. (2006). Layered Heterometallic Iodoplumbate Containing a Novel Pb3Cu6I16 Net: Structure and Optical Properties. Inorganic Chemistry, 45(26), 10437–10439. https://doi.org/10.1021/ic061827i

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