Synthesis, Structure, and Magnetic Properties of Sr₂NiOsO₆ and Ca₂NiOsO₆:  Two New Osmium-Containing Double Perovskites

Author(s)

René Macquart, University of South Carolina - Columbia
Seung-Joo Kim, University of South Carolina - Columbia
William R. Gemmill, University of South Carolina - Columbia
Judith K. Stalick, National Institute of Standards and Technology, Gaithersburg, Maryland
Yongjae Lee, Yonsei University
Thomas Vogt, University of South Carolina - Columbia
Hans-Conrad zur Loye, University of South Carolina - ColumbiaFollow

Document Type

Paper

Subject Area(s)

Chemistry

Abstract

Two new double perovskite oxides, Ca₂NiOsO₆ and Sr₂NiOsO₆, have been prepared as polycrystalline powders by solid state synthesis. The two oxides were structurally characterized by variable-temperature powder neutron diffraction. Ca₂NiOsO₆ was found to adopt a monoclinic structure (P₂₁/n), while Sr₂NiOsO₆ was found to be tetragonal (I4/m). Magnetic susceptibility measurements indicate that Ca₂NiOsO₆ orders in a canted antiferromagnetic state at about 175 K while Sr₂NiOsO₆ orders antiferromagnetically at about 50 K.

Digital Object Identifier (DOI)

https://doi.org/10.1021/ic051045+

Publication Info

Published in Inorganic Chemistry, Volume 44, Issue 26, 2005, pages 9676-9683.

© Inorganic Chemistry 2005, American Chemical Society.

APA Citation

Macquart, R., Kim, S.-J., Gemmill, W., Stalick, J., Lee, Y., Vogt, T., & zur Loye, H.-C. (2005). Synthesis, Structure, and Magnetic Properties of Sr₂NiOsO₆ and Ca₂NiOsO₆: Two New Osmium-Containing Double Perovskites. Inorganic Chemistry, 44(26), 9676–9683. https://doi.org/10.1021/ic051045+

Rights

© Inorganic Chemistry 2005, American Chemical Society.