Synthesis, Characterization, and Crystal Structures of Novel Coordination Compounds Assembled from the Reaction between the Asymmetric, Chelating Ligand 2-(4-Pyridyl)Thiazole-4-Carboxylic Acid with Zn+2 and Ag+ Ions

Document Type

Paper

Subject Area(s)

Chemistry

Abstract

Three new coordination polymers containing 2-(4-pyridyl)thiazole-4-carboxylate (pytac=C9H5N2O2S) and zinc or silver have been synthesized solvothermally, isolated, and characterized by single crystal X-ray diffraction, powder X-ray diffraction, and thermogravimetric analysis. ZnF(pytac)·(H2O) (1), which crystallizes in the space group Fdd2, a=14.7252(12) Å, b=45.925(4) Å, c=6.1678(5) Å and Zn(pytac)2·(H2O)4.3 (2), which crystallizes in the space group P21/c, a=12.923(3) Å, b=17.763(4) Å, c=9.902(2) Å, β=100.762(5)°, contain sheets that in the case of (1) are connected into a 3D assembly via hydrogen bonding, while Ag(pytac)·H2O (3), which crystallizes in the chiral space group P212121, a=7.0373(5) Å, b=10.4399(7) Å, c=13.3105(9) Å, forms a channel-containing 3D (10,3)-a chiral framework.

Digital Object Identifier (DOI)

https://doi.org/10.1016/j.molstruc.2006.03.034

Rights

© Journal of Molecular Structure 2006, Elsevier.

APA Citation

Ellsworth, J., Su, C.-Y., Khaliq, Z., Hipp, R., Goforth, A., Smith, M., & zur Loye, H.-C. (2006). Synthesis, Characterization, and Crystal Structures of Novel Coordination Compounds Assembled from the Reaction between the Asymmetric, Chelating Ligand 2-(4-Pyridyl)Thiazole-4-Carboxylic Acid with Zn+2 and Ag+ Ions. Journal of Molecular Structure, 794(1–3), 86–94. https://doi.org/10.1016/j.molstruc.2006.03.034

Link to Record

Share

COinS