The Crystal Growth and Magnetic Properties of Ln₂LiIrO₆ (Ln=La, Pr, Nd, Sm, Eu)

Author(s)

Samuel J. Mugavero III, University of South Carolina - Columbia
Mark D. Smith, University of South Carolina - ColumbiaFollow
Hans-Conrad zur Loye, University of South Carolina - ColumbiaFollow

Document Type

Paper

Subject Area(s)

Chemistry

Abstract

Single crystals of a series of lanthanide lithium iridium oxides, Ln₂LiIrO₆ (Ln=La, Pr, Nd, Sm, Eu) with the double perovskite structure have been grown from molten LiOH/KOH fluxes. The compounds crystallize in a distorted 1:1 rock salt lattice of Li⁺ and Ir⁵⁺ cations in the monoclinic space group P₂₁/n. The magnetic susceptibilities of Ln₂LiIrO₆ (Ln=Pr, Nd, Sm, Eu) are presented.

Digital Object Identifier (DOI)

https://doi.org/10.1016/j.jssc.2004.10.033

Publication Info

Published in Journal of Solid State Chemistry, Volume 178, Issue 1, 2004, pages 200-206.

Rights

© Journal of Solid State Chemistry 2004, Elsevier.

APA Citation

Mugavero, S., Smith, M., & zur Loye, H.-C. (2004). The Crystal Growth and Magnetic Properties of Ln₂LiIrO₆ (Ln=La, Pr, Nd, Sm, Eu). Journal of Solid State Chemistry, 178(1), 200–206. https://doi.org/10.1016/j.jssc.2004.10.033