Nickel Pyrazinecarboxylate: A New 1D Coordination Polymer

Author(s)

Kathryn L. Seward, University of South Carolina - Columbia
Joseph M. Ellsworth, University of South Carolina - Columbia
Mark D. Smith, University of South Carolina - ColumbiaFollow
Hans-Conrad zur Loye, University of South Carolina - ColumbiaFollow

Document Type

Article

Subject Area(s)

Chemistry

Abstract

A novel three-dimensional coordination polymer [Ni(pca)2(H₂O)]n (1) (pca = 2-pyrazinecarboxylate) has been synthesized by refluxing NiCl₂·(H₂O)₆ with pcaH (pcaH = 2-pyrazinecarboxcylic acid). Complex 1 contains one-dimensional zigzag chains that are H-bonded to adjacent chains, generating a three-dimensional network that crystallizes in the P212121 space group, and is isostructural with a previous structure containing Co (Liang et al. Inorg Chim Acta 328:152–158, 2002). In structure 1, a = 7.79(6), b = 9.90(8), and c = 14.90(12) Å.

Digital Object Identifier (DOI)

https://doi.org/10.1007/s10870-008-9321-2

Publication Info

Published in Journal of Chemical Crystallography, Volume 38, Issue 4, 2008, pages 239-242.

Rights

© Journal of Chemical Crystallography 2008, Spinger Nature.

APA Citation

Seward, K., Ellsworth, J., Smith, M., & zur Loye, H.-C. (2008). Nickel Pyrazinecarboxylate: A New 1D Coordination Polymer. Journal of Chemical Crystallography, 38(4), 239–242. https://doi.org/10.1007/s10870-008-9321-2