Nickel Pyrazinecarboxylate: A New 1D Coordination Polymer

Document Type

Article

Subject Area(s)

Chemistry

Abstract

A novel three-dimensional coordination polymer [Ni(pca)2(H2O)]n (1) (pca = 2-pyrazinecarboxylate) has been synthesized by refluxing NiCl2·(H2O)6 with pcaH (pcaH = 2-pyrazinecarboxcylic acid). Complex 1 contains one-dimensional zigzag chains that are H-bonded to adjacent chains, generating a three-dimensional network that crystallizes in the P212121 space group, and is isostructural with a previous structure containing Co (Liang et al. Inorg Chim Acta 328:152–158, 2002). In structure 1, a = 7.79(6), b = 9.90(8), and c = 14.90(12) Å.

Digital Object Identifier (DOI)

https://doi.org/10.1007/s10870-008-9321-2

Rights

© Journal of Chemical Crystallography 2008, Spinger Nature.

APA Citation

Seward, K., Ellsworth, J., Smith, M., & zur Loye, H.-C. (2008). Nickel Pyrazinecarboxylate: A New 1D Coordination Polymer. Journal of Chemical Crystallography, 38(4), 239–242. https://doi.org/10.1007/s10870-008-9321-2

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