Catena-Poly[[Bis(α-Thenoyltrifluoroacetonato)Copper(II)]-μ-1,4-Di-4-Pyridyl-2,3-Diazabuta-1,3-Diene]

Author(s)

William J. Perkins, Francis Marion University
Tamara Maxwell, Francis Marion University
Mark D. Smith, University of South Carolina - ColumbiaFollow
LeRoy Peterson Jr., Francis Marion University
Hans-Conrad zur Loye, University of South Carolina - ColumbiaFollow

Document Type

Article

Subject Area(s)

Chemistry

Abstract

In the one-dimensional title polymer, [Cu(C₈H₄F₃O₂S)₂(C₁₂H₁₀N₄)]_n or [Cu(L)₂(tta)₂] [tta is -thenoyltrifluoroacetonato and L is 1,4-bis(4-pyridyl)-2,3-diaza-1,3-butadiene], Cu²⁺ lies on a center of inversion. It is axially coordinated by two pyridyl N atoms from two different L ligands and equatorially coordinated by four O atoms from two chelating tta ligands. The ligand L propagates the one-dimensional chain structure by serving as a bridging ligand between two Cu octahedra via Cu-N coordinate bonds.

Digital Object Identifier (DOI)

https://doi.org/10.1107/S1600536805028631

Publication Info

Published in Acta Crystallographica Section E, Volume 61, Issue 10, 2005, pages m2047-m2049.

Rights

© Acta Crystallographica Section E 2005, International Union of Crystallography.

APA Citation

Perkins, W., Maxwell, T., Smith, M., Peterson, L., & zur Loye, H.-C. (2005). Catena-Poly[[Bis(α-Thenoyltrifluoroacetonato)Copper(II)]-μ-1,4-Di-4-Pyridyl-2,3-Diazabuta-1,3-Diene]. Acta Crystallographica Section E, 61(10), m2047–m2049. https://doi.org/10.1107/S1600536805028631