Date of Award
Fall 2019
Document Type
Open Access Dissertation
Department
Chemistry and Biochemistry
First Advisor
Chuanbing Tang
Second Advisor
Brian C. Benicewicz
Abstract
Metal-containing polyelectrolytes (or metallo-polyelectrolytes) represent a new class of polymeric materials with distinct properties compared to traditional organo- polyelectrolytes or neutral metallopolymers. This emerging class of synthetic materials is ubiquitous for a myriad of utilities ranging from traditional electrolyte chemistry to biomedicals to sustainable applications, to name just a few. This dissertation work is focused on the design, synthesis, characterization and application of advanced metallo- cations and metallo-polyelectrolytes for energy storage applications. First, a template method to prepare metallo-polyelectrolytes based on cationic cobaltocene and polyethylene backbone was described. The resulting membranes are mechanically tough, ionically conductive and chemically inert. Second, a family of substituted cobaltocenium cations and their derivatives was designed by theoretical calculation and experimentally synthesized for the first time. The redox behaviors and chemical stability of these metallo- cations were systematically examined and complemented those of state-of-the-art organic cations. Furthermore, substituted cobaltocene cation was integrated to construct solid polyelectrolyte membranes for energy storage devices (e.g. solid-state alkaline fuel cells). The device performance of these polyelectrolytes under highly basic and oxidative environments is also discussed.
Rights
© 2019, Tianyu Zhu
Recommended Citation
Zhu, T.(2019). Cationic Cobaltocene Derivatives and Polyelectrolyte Membranes for Energy Storage Applications. (Doctoral dissertation). Retrieved from https://scholarcommons.sc.edu/etd/5563