Unsteady State Behavior of CO Oxidation Over A Supported Pt Catalyst In The Millibar Range
Engineering, Chemical Engineering, Catalysis and Reaction Engineering
The formation and characterization of nanometer-size, ohmic contacts to 𝑛n-type GaAs substrates are described. The nanocontacts are formed between a single-crystalline, nanometer-size Au cluster and a GaAs structure capped with layer of low-temperature-grown GaAs (LTG:GaAs). An organic monolayer of xylyl dithiol (p(p-xylene-α,α′α,α′- dithiol; C8H10S2)C8H10S2) provides mechanical and electronic tethering of the Au cluster to the LTG:GaAs surface. The I(V)I(V) data of the Au cluster/xylyl dithiol/GaAs show ohmic contact behavior with good repeatability between various clusters distributed across the surface. The specific contact resistance is determined to be 1×10 −6 Ω cm 2. Current densities above 1×106A/cm2 have been observed.
Digital Object Identifier (DOI)
Published in Reaction Kinetics and Catalysis Letters, Volume 65, Issue 1, 1998, pages 3-8.
© Reaction Kinetics and Catalysis Letters, 1998, Springer-Verlag
Bonilla, G., Pletcher, D.T., Haas, G., Lauterbach, A.J. (1998). Unsteady-state behavior of CO oxidation over a supported Pt catalyst in the Millibar range. Reaction Kinetics and Catalysis Letters, 65(1), 3-8.