Document Type


Subject Area(s)

Chemical Engineering


Predictions of the electrical energy cost for NaOH production are determined as a function of the independent operating variables and diaphragm characterizing properties. The predictions are based on data from a statistically designed experiment, a simple model of a diaphragm-type electrolyzer, a simple model of the cell voltage losses, and parameter estimation techniques. The data were obtained over a sufficiently large range of operating conditions so that the resulting design equation may be industrially useful. The simple model of the diaphragm is based on the mass transport of the hydroxyl ion, a linear potential gradient, and is presented in terms of measurable diaphragm properties.These properties are the thickness of the diaphragm (t) and a resistivity ratio, /0, where is the resistivity of the diaphragm filled with electrolyte and 0 is the resistivity of the electrolyte (this ratio may come to be known as the MacMullin number, NM). It is shown that, according to the model of the cell, the caustic yield or current efficiency of the diaphragm cell depends on the product of NM and t and not on each separately. The simple model of the cell voltage considers the diaphragm voltage drop, anode and cathode kinetics, and the bubble-filled brine-gap voltage drop. Parameter estimation techniques are used to determine the best values of the diffusion coefficient, average specific conductivity, exchange current densities, and transfer coefficients; these parameters and the simple models provide a design equation for the electrical energy cost of NaOH production using a diaphragm cell. The design equation is used to predict aminimum electrical-energy cost at a particular NMt.


© The Electrochemical Society, Inc. 1985. All rights reserved. Except as provided under U.S. copyright law, this work may not be reproduced, resold, distributed, or modified without the express permission of The Electrochemical Society (ECS). The archival version of this work was published in Journal of the Electrochemical Society.

Publisher's Version:

DOI: 10.1149/1.2113965