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Subject Area(s)

Chemical Engineering


The hybrid sulfur cycle has been investigated as a means to produce clean hydrogen efficiently on a large scale by first decomposing H2SO4 to SO2, O2, and H2O and then electrochemically oxidizing SO2 back to H2SO4 with the cogeneration of H2. Thus far, it has been determined that the total cell potential for the hybrid sulfur electrolyzer is controlled mainly by water transport in the cell. Water is required at the anode to participate in the oxidation of SO2 to H2SO4 and to hydrate the membrane. In addition, water transport to the anode influences the concentration of the sulfuric acid produced. The resulting sulfuric acid concentration at the anode influences the equilibrium potential of and the reaction kinetics for SO2 oxidation and the average conductivity of the membrane. A final contribution to the potential loss is the diffusion of SO2 through the sulfuric acid to the catalyst site. Here, we extend our understanding of water transport to predict the individual contributions to the total cell potential.


© The Electrochemical Society, Inc. 2010. All rights reserved. Except as provided under U.S. copyright law, this work may not be reproduced, resold, distributed, or modified without the express permission of The Electrochemical Society (ECS). The archival version of this work was published in the Journal of the Electrochemical Society.

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DOI: 10.1149/1.3397901