Di-μ-Iodo-Bis[Diiodo(1,10-Phenanthroline)Bismuth(III)]

Document Type

Article

Subject Area(s)

Chemistry

Abstract

The title bismuth-iodide compound, [Bi2I6(C12H8N2)2], has been synthesized solvothermally by reacting BiI3, Mn(CH3COO)2·4H2O, and 1,10-phenanthroline in an ethanol/water solvent mixture. The compound contains two bismuth centers that are each coordinated by a phenanthroline ligand and two terminal iodide ligands, and the bismuth centers are bridged via two additional iodide ligands to form a molecular dimer. The asymmetric unit of the compound consists of one half of a single dimer molecule located on a crystallographic inversion center.

Digital Object Identifier (DOI)

https://doi.org/10.1107/S1600536806041997

APA Citation

Terhansy, M., Goforth, A., Smith, M., Peterson, L., & zur Loye, H.-C. (2006). Di-μ-Iodo-Bis[Diiodo(1,10-Phenanthroline)Bismuth(III)]. Acta Crystallographica Section E, 62(11), m2987-2m989. https://doi.org/10.1107/S1600536806041997

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