Document Type

Article

Subject Area(s)

Chemistry

Abstract

The new iodobismuthate compound (C13H11N2O)4[Bi6I22] has been synthesized solvothermally by reacting BiI3, Zn(NO3)2·6H2O and 4,5-diazafluoren-9-one in a water/ethanol solvent mixture. The asymmetric unit of the compound contains two independent [N-ethyl-4,5-dafo]+ cations and one-half of a centrosymmetric [Bi6I22]4- anion. The average terminal Bi-I, Bi-2-I and Bi-3-I bond lengths in the anion are 2.8923 (2), 3.1403 (2) and 3.3022 (2) Å, respectively.

Digital Object Identifier (DOI)

https://doi.org/10.1107/S1600536806043960

APA Citation

Terhansy, M., Goforth, A., Smith, M., Peterson, L., & zur Loye, H.-C. (2006). Tetrakis(N-Ethyl-9-Oxo-4-Azonia-5-Aza-9H-Fluorene) Tetra-μ3-Iodo-Hexa-μ2-Iodo-Dodecaiodohexabismuthate. Acta Crystallographica Section E, 62(12), m3269–m3271. https://doi.org/10.1107/S1600536806043960

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