The new iodobismuthate compound (C13H11N2O)4[Bi6I22] has been synthesized solvothermally by reacting BiI3, Zn(NO3)2·6H2O and 4,5-diazafluoren-9-one in a water/ethanol solvent mixture. The asymmetric unit of the compound contains two independent [N-ethyl-4,5-dafo]+ cations and one-half of a centrosymmetric [Bi6I22]4- anion. The average terminal Bi-I, Bi-2-I and Bi-3-I bond lengths in the anion are 2.8923 (2), 3.1403 (2) and 3.3022 (2) Å, respectively.
Digital Object Identifier (DOI)
Published in Acta Crystallographica Section E, Volume 62, Issue 12, 2006, pages m3269-m3271.
© Acta Crystallographica Section E 2006, International Union of Crystallography.
Terhansy, M., Goforth, A., Smith, M., Peterson, L., & zur Loye, H.-C. (2006). Tetrakis(N-Ethyl-9-Oxo-4-Azonia-5-Aza-9H-Fluorene) Tetra-μ3-Iodo-Hexa-μ2-Iodo-Dodecaiodohexabismuthate. Acta Crystallographica Section E, 62(12), m3269–m3271. https://doi.org/10.1107/S1600536806043960