Document Type



Herein, we report the first example of a crystalline metal–donor–fullerene framework, in which control of the donor–fullerene mutual orientation was achieved through chemical bond formation, in particular, by metal coordination. The 13C cross-polarization magic-angle spinning NMR spectroscopy, X-ray diffraction, and time-resolved fluorescence spectroscopy were performed for comprehensive structural analysis and energy-transfer (ET) studies of the fulleretic donor–acceptor scaffold. Furthermore, in combination with photoluminescence measurements, the theoretical calculations of the spectral overlap function, Förster radius, excitation energies, and band structure were employed to elucidate the photophysical and ET processes in the prepared fulleretic material. We envision that the well-defined fulleretic donor–acceptor materials could contribute not only to the basic science of fullerene chemistry but would also be used towards effective development of organic photovoltaics and molecular electronics.

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© 2016 The Authors. Published by Wiley-VCH Verlag GmbH & Co. KGaA.

This is an open access article under the terms of the Creative Commons Attribution-NonCommercial License, which permits use, distribution and reproduction in any medium, provided the original work is properly cited and is not used for commercial purposes.

APA Citation

Williams, D. E., Dolgopolova, E. A., Godfrey, D. C., Ermolaeva, E. D., Pellechia, P. J., Greytak, A. B., Smith, M. D., Avdoshenko, S. M., Popov, A. A., & Shustova, N. B. (2016). Fulleretic well‐defined scaffolds: Donor–fullerene alignment through metal coordination and its effect on Photophysics. Angewandte Chemie International Edition, 55(31), 9070–9074.