[Ru(2,2′-bipy)3]2[Bi4I16]: A Bimetallic Inorganic–Organic Complex Consisting of a D-Metal Coordination Cation and a Polynuclear Iodobismuthate Anion
Document Type
Paper
Subject Area(s)
Chemistry
Abstract
The crystal structure of [Ru(2,2′-bipy)3]2[Bi4I16] (2,2′-bipy = 2,2′-bipyridine) contains the photochemically active coordination cation [Ru(2,2′-bipy)3]2+ and the large, polynuclear [Bi4I16]4− anion. [Bi4I16]4−consists of four edge-sharing BiI6 octahedra and is derived from the neutral, semiconductor BiI3 by uptake of I−. The title compound is a rare example of a mixed-metal halobismuthate material [crystal data C60H48Bi4I16N12Ru2: triclinic, P1¯, a = 12.2963(7) Å, b = 14.0147(8) Å, c = 14.7234(8) Å, α = 70.1900(1)°, β = 69.2010(1)°, γ = 72.6570(1)°].
Digital Object Identifier (DOI)
https://doi.org/10.1016/j.inoche.2005.03.028
Publication Info
Published in Inorganic Chemistry Communications, Volume 8, Issue 8, 2005, pages 684-688.
© Inorganic Chemistry Communications 2005, Elsevier.
APA Citation
Goforth, A., Gardinier, J., Smith, M., Peterson, L., & zur Loye, H.-C. (2005). [Ru(2,2′-bipy)3]2[Bi4I16]: A Bimetallic Inorganic–Organic Complex Consisting of a D-Metal Coordination Cation and a Polynuclear Iodobismuthate Anion. Inorganic Chemistry Communications, 8(8), 684–688. https://doi.org/10.1016/j.inoche.2005.03.028
Rights
© Inorganic Chemistry Communications 2005, Elsevier.