Title

Strategy to Eliminate Catalyst Hot-Spots in the Partial Oxidation of Methane: Enhancing its Activity for Direct Hydrogen Production by Reducing the Reactivity of Lattice Oxygen

Document Type

Article

Subject Area(s)

Chemical Engineering, Catalysis and Reaction Engineering

Abstract

Hydrogen can be produced over Er2O3 in methane oxidation (oxygen/methane = 26). The reactivity of lattice oxygen in the catalyst plays a main role in the conversion of surface hydroxylspecies to hydrogen or water. Adding a rare earth element into a catalyst can reduce the reactivity of lattice oxygen, resulting in increased hydrogen production, to eliminate catalyst hot-spots.