Poly[[(μ-2,2'-bipyrimidine-κ⁴N¹,N¹':N³,N³')(μ-sulfato-κ²O:O')zinc(II)] monohydrate]

Author(s)

Aaron Oxendine, Francis Marion University
Jennifer Kelley, Francis Marion University
LeRoy Peterson Jr., Francis Marion University
Mark D. Smith, University of South Carolina - ColumbiaFollow
Hans-Conrad zur Loye, University of South Carolina - ColumbiaFollow

Document Type

Article

Subject Area(s)

Chemistry

Abstract

In the title compound, {[Zn(SO₄)(C₈H₆N₄)]·H₂O}_n, the Zn^II atom is in a distorted octahedral environment. The Zn^II atoms are bridged by both 2,2'-bipyrimidine and sulfate ligands, thus forming a three-dimensional polymeric metal-organic solid that contains uncoordinated water molecules in the interstitial space. O-HO hydrogen bonding consolidates the crystal structure.

Digital Object Identifier (DOI)

https://doi.org/10.1107/S1600536810001649

Publication Info

Published in Acta Crystallographica Section E, Volume E66, Issue 2, 2010, pages m220-.

Rights

© Acta Crystallographica Section E 2010, International Union of Crystallography.

The publisher's version can be found here.

APA Citation

Oxendine, A., Kelley, J., Peterson, L., Smith, M., & zur Loye, H.-C. (2010). Poly[[(μ-2,2’-bipyrimidine-κ⁴N_¹,N_¹’:N_³,N_³’)(μ-sulfato-κ_²O:O’)zinc(II)] monohydrate]. Acta Crystallographica Section E, E66(2), m220. https://doi.org/10.1107/S1600536810001649