Trisodium Dicalcium Bismuth Hexaoxide

Author(s)

Irina V. Puzdrjakova, University of South Carolina - Columbia
Rene B. Macquart, University of South Carolina - Columbia
Mark D. Smith, University of South Carolina - ColumbiaFollow
Hans-Conrad zur Loye, University of South Carolina - ColumbiaFollow

Document Type

Article

Subject Area(s)

Chemistry

Abstract

Single crystals of the title compound, Na₃Ca₂BiO₆, were grown from a high-temperature reactive flux solution of Na₂CO₃. Na₃Ca₂BiO₆ crystallizes as an ordered rock-salt structure (space group Fddd), in which the octahedral holes in the oxide array are filled by an ordered 3:2:1 arrangement of Na⁺, Ca²⁺ and Bi⁵⁺ cations. All atoms except for one O atom lie on special positions; site symmetries are as follows: Bi 222, Ca 2, Na 222 and 2, O 2.

Digital Object Identifier (DOI)

https://doi.org/10.1107/S1600536807008690

Publication Info

Published in Acta Crystallographica Section E, Volume 63, Issue 3, 2007, pages i95-i96.

Rights

© Acta Crystallographica Section E 2007, International Union of Crystallography.

Publisher's version available here.

APA Citation

Puzdrjakova, I., Macquart, R., Smith, M., & zur Loye, H.-C. (2007). Trisodium Dicalcium Bismuth Hexaoxide. Acta Crystallographica Section E, 63(3), i95–i96. https://doi.org/10.1107/S1600536807008690