Tetrakis(N-Ethyl-9-Oxo-4-Azonia-5-Aza-9H-Fluorene) Tetra-μ₃-Iodo-Hexa-μ₂-Iodo-Dodecaiodohexabismuthate

Author(s)

Meredith A. Tershany, University of South Carolina - Columbia
Andrea M. Goforth, University of South Carolina - Columbia
Mark D. Smith, University of South Carolina - ColumbiaFollow
LeRoy Peterson Jr., Francis Marion University
Hans-Conrad zur Loye, University of South Carolina - ColumbiaFollow

Document Type

Article

Subject Area(s)

Chemistry

Abstract

The new iodobismuthate compound (C₁₃H₁₁N₂O)₄[Bi₆I₂₂] has been synthesized solvothermally by reacting BiI₃, Zn(NO₃)₂·6H₂O and 4,5-diazafluoren-9-one in a water/ethanol solvent mixture. The asymmetric unit of the compound contains two independent [N-ethyl-4,5-dafo]⁺ cations and one-half of a centrosymmetric [Bi₆I₂₂]^4- anion. The average terminal Bi-I, Bi-₂-I and Bi-₃-I bond lengths in the anion are 2.8923 (2), 3.1403 (2) and 3.3022 (2) Å, respectively.

Digital Object Identifier (DOI)

https://doi.org/10.1107/S1600536806043960

Publication Info

Published in Acta Crystallographica Section E, Volume 62, Issue 12, 2006, pages m3269-m3271.

Rights

© Acta Crystallographica Section E 2006, International Union of Crystallography.

APA Citation

Terhansy, M., Goforth, A., Smith, M., Peterson, L., & zur Loye, H.-C. (2006). Tetrakis(N-Ethyl-9-Oxo-4-Azonia-5-Aza-9H-Fluorene) Tetra-μ₃-Iodo-Hexa-μ₂-Iodo-Dodecaiodohexabismuthate. Acta Crystallographica Section E, 62(12), m3269–m3271. https://doi.org/10.1107/S1600536806043960