catena-Poly[[bis(α-thenoyltrifluoroacetonato-κ²O,O')copper(II)]-μ-1,4-di-3-pyridyl-2,3-diaza-1,3-butadiene-κ²N:N']

Author(s)

William J. Perkins, Francis Marion University
Tamar Maxwell, Francis Marion University
Ken B. Williams, Francis Marion University
Andrea M. Goforth, University of South Carolina - Columbia
Mark D. Smith, University of South Carolina - ColumbiaFollow
LeRoy Peterson Jr., Francis Marion University
Hans-Conrad zur Loye, University of South Carolina - ColumbiaFollow

Document Type

Article

Subject Area(s)

Chemistry

Abstract

The title compound, [Cu(C₈H₄F₃O₂S)₂(C₁₂H₁₀N₄)]_n or [Cu(tta)₂(L2)₂]_n (L2 = 1,4-di-3-pyridyl-2,3-diaza-1,3-butadiene and tta = -thenoyltrifluoroacetonate), consists of undulating chains containing two crystallographically distinct Cu^II centers that are each located on inversion centers. Each Cu^II center exhibits distorted octahedral coordination provided by two pyridyl N atoms from two equivalent L2 ligands and four O atoms from two equivalent tta ligands. The chains interact through weak C-FH-C contacts.

Digital Object Identifier (DOI)

https://doi.org/10.1107/S1600536807000311

Publication Info

Published in Acta Crystallographica Section E, Volume 63, Issue 2, 2007, pages m423-m425.

Rights

© Acta Crystallographica Section E 2007, International Union of Crystallography.

Publisher's version available here.

APA Citation

Perkins, W., Maxwell, T., Williams, K., Goforth, A., Smith, M., Peterson, L., & zur Loye, H.-C. (2007). Catena-Poly[[bis(α-thenoyltrifluoroacetonato-κ²O,O’)copper(II)]-μ-1,4-di-3-pyridyl-2,3-diaza-1,3-butadiene-κ²N:N’]. Acta Crystallographica Section E, 63(2), m423–m425. https://doi.org/10.1107/S1600536807000311