Ln14Na3Ru6O36 (Ln = Pr, Nd): Two New Complex Lanthanide-Containing Oxides of Ruthenium
The lanthanide-containing ruthenium oxides Ln14Na3Ru6O36 (Ln = Pr, Nd) were prepared as single crystals from molten sodium hydroxide. The two compounds crystallize in the rhombohedral space group R3̄c with cell constants of a = 9.7380(2) and 9.6781(2) Å and c = 55.5716(18) and 55.4156(18) Å for Ln14Na3Ru6O36 (Ln = Pr, Nd), respectively. The structure of the two compounds is composed of two types of slabs that alternate in an AB fashion. Each slab consists of three layers and are arranged to yield a unit cell with a 12-layer structure. Both compounds exhibit magnetic behavior consistent with canted antiferromagnetism.
Published in Inorg. Chem, Volume 46, Issue 6, 2007, pages 2132-2138.
Ln14Na3Ru6O36 (Ln = Pr, Nd): Two New Complex Lanthanide-Containing Oxides of RutheniumWilliam R. Gemmill,Mark D. Smith, and, and Hans-Conrad zur Loye* Inorganic Chemistry 2007 46 (6), 2132-2138