Changing an ether to a ketone within the framework of a bis-urea macrocycle has little effect on the supramolecular assembly of this building block into porous crystals but introduces a triplet sensitizer into the framework that dramatically alters the photochemical reactions of included guests.
Digital Object Identifier (DOI)
Published in Chemical Communications, Volume 33, 2008, pages 3909-3911.
© Chemical Communications 2008, Royal Society of Chemistry.
Dewal, M., Xu, Y., Yang, J., Mohammed, F., Smith, M., & Shimizu, L. (2008). Manipulating the Cavity of a Porous Material Changes the Photoreactivity of Included Guests. Chemical Communications, 33, 3909–3911. https://doi.org/10.1039/B805895D