Changing an ether to a ketone within the framework of a bis-urea macrocycle has little effect on the supramolecular assembly of this building block into porous crystals but introduces a triplet sensitizer into the framework that dramatically alters the photochemical reactions of included guests.
Published in Chemical Communications, Volume 33, 2008, pages 3909-3911.
© Chemical Communications 2008, Royal Society of Chemistry
Dewal, M. B., Xu, Y., Yang, J., Mohammed, F., Smith, M. D., & Shimizu, L. S. (2008). Manipulating the cavity of a porous material changes the photoreactivity of included guests. Chemical Communications, 33, 3909-3911.