Analysis of Electrokinetic Data by Parameter Estimation and Model Discrimination Techniques

Author(s)

Prosper K. Adanuvor, Texas A & M University - College Station
Ralph E. White, University of South Carolina - ColumbiaFollow

Document Type

Article

Subject Area(s)

Chemical Engineering

Abstract

An alternative approach to classical methods of electrochemical data analysis is presented. This alternative method is based on nonlinear parameter estimation and model discrimination techniques. The method is used to obtain the relevant kinetic and transport parameters and to elucidate the kinetic mechanism of O₂ reduction at carbon and silver electrodes in alkaline electrolytes.

Publication Info

Journal of the Electrochemical Society, 1988, pages 1887-1898.

© The Electrochemical Society, Inc. 1988. All rights reserved. Except as provided under U.S. copyright law, this work may not be reproduced, resold, distributed, or modified without the express permission of The Electrochemical Society (ECS). The archival version of this work was published in the Journal of the Electrochemical Society.

http://www.electrochem.org

DOI: 10.1149/1.2096174

http://dx.doi.org/10.1149/1.2096174

Rights

© The Electrochemical Society, Inc. 1988. All rights reserved. Except as provided under U.S. copyright law, this work may not be reproduced, resold, distributed, or modified without the express permission of The Electrochemical Society (ECS). The archival version of this work was published in the Journal of the Electrochemical Society.

http://www.electrochem.org

DOI: 10.1149/1.2096174

http://dx.doi.org/10.1149/1.2096174